NO ICE HYDROGENATION: A SOLID PATHWAY TO NH2OH FORMATION IN SPACE

作者:Congiu Emanuele*; Fedoseev Gleb; Ioppolo Sergio; Dulieu Francois; Chaabouni Henda; Baouche Saoud; Lemaire Jean Louis; Laffon Carine; Parent Philippe; Lamberts Thanja; Cuppen Herma M; Linnartz Harold
来源:Astrophysical Journal Letters, 2012, 750(1): L12.
DOI:10.1088/2041-8205/750/1/L12

摘要

Icy dust grains in space act as catalytic surfaces onto which complex molecules form. These molecules are synthesized through exothermic reactions from precursor radicals and, mostly, hydrogen atom additions. Among the resulting products are species of biological relevance, such as hydroxylamine-NH2OH-a precursor molecule in the formation of amino acids. In this Letter, laboratory experiments are described that demonstrate NH2OH formation in interstellar ice analogs for astronomically relevant temperatures via successive hydrogenation reactions of solid nitric oxide (NO). Inclusion of the experimental results in an astrochemical gas-grain model proves the importance of a solid-state NO + H reaction channel as a starting point for prebiotic species in dark interstellar clouds and adds a new perspective to the way molecules of biological importance may form in space.

  • 出版日期2012-5-1