A new organic transformation by introducing crotyl/allyltrifluoroborates in cross-coupling reaction with aroyl chlorides

作者：Al Masum Mohammad^*; Liu Kwei Yu

来源：Tetrahedron Letters, 2011, 52(39): 5090-5093.

DOI：10.1016/j.tetlet.2011.07.107

• Cross-coupling
• Potassium crotyl- and allyltrifluoroborates
• Aroyl chlorides
• Crotonophenones

Microwave irradiated PdCl(2)(d(t)bpf) catalyzed direct cross-coupling reaction of aroyl chlorides with potassium crotyl/allyltrifluoroborates has been developed. Regioselectivity of the cross-coupling product is varied from crotyltrifluoroborate to allyltrifluoroborate.

• 出版日期2011-9-28