Arene-perfluoroarene interactions for crystal engineering of metal complexes: Controlled self-assembly of paddle-wheel dimers

作者：Itoh Takahiro^*; Kondo Mio; Kanaike Mari; Masaoko Shigeyuki

来源：CrystEngComm, 2013, 15(31): 6122-6126.

DOI：10.1039/c3ce40777b

We show a new approach to control the self-assembly of paddle-wheel dimers by intermolecular multipoint arene-perfluoroarene interactions. Two types of complexes, I-shaped Rh-2(O2CCF3)(2)(L)(2) (3-pentanone)(2) (1) and cross-shaped Cu-2(L)(4)(THF)(2)(2) were synthesized to afford 1D chain and 2D square-grid sheet structures, respectively.

• 出版日期2013