Weak interactions and 2D layer structure of a new ion-pair complex bis(1-benzyl-4-methylquinolinium)-bis(maleonitriledithiolato)nickel(II)

作者：Zhou Jia Rong; Ni Chun Lin^*

来源：Chinese Journal of Structural Chemistry, 2007, 26(11): 1263-1266.

• 1-benzyl-4-methylquinolinium
• bis(maleonitriledithiolate)nickelate(II) complex
• weak interactions
• 2D layer structure

A new ion-pair complex, [BzMeQl](2)[Ni(mnt)(2)] 1 ([BzMeQl]( ) = 1-benzyl-4-methylquinolinium, mnt(2-) = maleonitriledithiolate) has been synthesized and structurally characterized by IR, ESI-MS and X-ray diffraction methods. Complex 1 is of triclinic, space group P-1(-), with a = 9.079(2), b = 10.154(2), c = 11.243(2) angstrom, alpha = 81.58(1), beta = 69.63(1), gamma = 68.02(1)degrees, V = 940.1(3) angstrom(3), D-c = 1.427 g/cm(3), Z = 1, F(000) = 418 and R = 0.0442. A 2D layer structure is formed via the cation-cation pi center dot center dot pi and C-H center dot center dot center dot pi interactions observed in the solid state of the complex.

• 出版日期2007
• 单位华南农业大学