A perfluorous polyphenyl dendritic shell for the protection of a photosensitizing porphyrazine core

作者:Loeser Patricia; Winzenburg Andreas; Faust Ruediger*
来源:Chemical Communications, 2013, 49(82): 9413-9415.
DOI:10.1039/c3cc45442h

摘要

The implementation of thirty-two pentafluorophenyl groups in the periphery of a phthalocyanine analogue results in a photosensitizer with a pronounced resistance towards autophotooxidation. The synthesis relies on the microwave-assisted cycloaddition of terminal alkynes to tetrakis(pentafluorophenyl) cyclopentadienone, for which a new route was devised.

  • 出版日期2013

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