mu-Chlorido-bis({N-benzyl-N '-[2-(benzyl-amino)ethyl]ethane-1,2-diamine}chloridocopper(II)) chloride

作者：Liu Yu Fen^*; Xia Hai Tao; Wang Da Qi; Yang Shu Ping

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M2805-U1632.

DOI：10.1107/S1600536807051434

In the title compound, [Cu2Cl3(C18H25N3)(2)]Cl, the asymmetric unit consists of one half of a mu-chlorido-bis[{N-benzyl-N'-[2(benzylamino)ethyl]ethane-1,2-diamine}chloridocopper(II)] complex cation and one chloride anion lying on a twofold rotation axis. The two Cu-II centres are symmetry-related by a twofold rotation axis passing through the bridging Cl atom. The Cu atoms exhibit a distorted square-pyramidal coordination environment. The basal and apical Cu-Cl bond lengths are 2.254 (2) and 2.658 (2) angstrom, respectively. The Cu center dot center dot center dot Cu distance and Cu-Cl-Cu angle are 4.349 (6) angstrom and 109.8 (2)degrees, respectively. In the crystal structure, the molecules of the complex are linked into chains along b and a by C H center dot center dot center dot pi hydrogen bonds. The chloride anion links these chains along c into a three-dimensional network structure.

• 出版日期2007-11
• 单位淮海工学院; 聊城大学