Direct thermal intercalation of amine into layered MoO3

作者：Jing Yi; Pan Qingyi^*; Cheng Zhixuan; Dong Xiaowen; Xiang Yixian

来源：Materials Science and Engineering B-Solid State Materials for Advanced Technology, 2007, 138(1): 55-59.

DOI：10.1016/j.mseb.2007.01.015

• molybdenum trioxide
• intercalation
• layered material
• amine

Molybdenum oxide nanocomposites with layered structures were prepared directly from commercial bulk MoO3 using alkylamines as the guests. By using molybdenum oxide-amines as the starting materials, novel molybdenum oxide-dye composite was synthesized. On the basis of X-ray diffraction, scanning electron microscopy and infrared results, a possible arrangement of alkylamines guests in the interlayer space of molybdenum oxide has been proposed. Moreover, the interactions between the inorganic host and the organic guests have been discussed. A linear relationship is observed between the interlayer distance and the number of carbon atoms in n-alkyl chains.

• 出版日期2007-3-15
• 单位上海大学