Anionic polymerization of ethyl acrylate initiated by tetrabutylammonium azide: direct synthesis of end-clickable polyacrylate

作者：Kataoka Yuki; Kohsaka Yasuhiro^*; Kitaura Takehiro; Domae Shogo; Ishihara Shoya; Kitayama Tatsuki^*

来源：Polymer Chemistry, 2017, 8(26): 3858-3861.

DOI：10.1039/c7py00560a

Tetrabutylammonium azide was found to initiate the anionic polymerization of ethyl acrylate (EA) in the presence of alkyl-aluminum bisphenoxides in toluene to afford azide-end polymers with narrow molecular weight distributions in quantitative yields. The resulting polymers showed high enough reactivity for the copper-catalyzed azide-alkyne cycloaddition.

• 出版日期2017-7-14