An unexpected Lewis acids-catalyzed tandem ring-opening rearrangement of vinylcyclopropane ketone with aryl aldehyde

作者：Ren Jun; Bai Yu; Tao Weijie; Wang Zhongwen^*

来源：Tetrahedron Letters, 2014, 55(15): 2545-2547.

DOI：10.1016/j.tetlet.2014.03.035

• Cyclopropane
• Tandem reactions
• Rearrangement
• Ring opening

A novel tandem reaction of vinylcyclopropane ketone with benzaldehyde has been successfully developed. This provides a new method for the preparation of gamma-oxo-hexenone derivatives from easily accessible starting materials.

• 出版日期2014-4-9
• 单位南开大学