Going against the flow: Os(II)-to-Ru(II) energy transfer in rod-like polypyridyl chromophore

作者:Laramee Milette Baptiste; Hanan Garry S*
来源:Chemical Communications, 2017, 53(76): 10496-10499.
DOI:10.1039/c7cc03541a

摘要

The judicious design of a unique mixed-metal Ru-Os molecular rod led to the first photoinduced energy transfer from osmium-toruthenium in a polypyridyl complex. The absorbed light is directed from the osmium metal center to the peripheral ruthenium moieties, where only the low energy luminescence from the heteroleptic ruthenium phen-hpp complex was observed.

  • 出版日期2017-9-28