Novel palladium(II) and platinum(II) complexes of biocidal benzisothiazolinone (Bit); X-ray crystal structures of co-crystallised Bit/BitO and cis-Pd(en)(Bit(-1H))(2)center dot H2O

作者：Griffith Darren M^*; Haughey Aisleen; Chahal Sunisha; Mueller Bunz Helge; Marmion Celine J

来源：Inorganica Chimica Acta, 2010, 363(10): 2333-2337.

DOI：10.1016/j.ica.2010.02.005

• Platinum complexes
• Palladium complexes
• Benzisothiazolinone
• Biocide

Reaction of benzisothiazolinone (Bit), a well-known biocide, with the Pd(II) and Pt(II) am(m) ine precursors cis-[Pd(en)(H2O)(2)](NO3)(2) and cis-[Pt(NH3)(2)(H2O)(2)](NO3)(2) yielded cis-Pd(en)(Bit(-1H))(2) and cisPt( NH3)(2)(Bit(-1H))(2), respectively. Bit is bound to the metal centres in both cases through the deprotonated isothiazolinone N. The crystal structures of a Bit/BitO co-crystal and cis-Pd(en)(Bit(-1H))(2)center dot H2O are also described.

• 出版日期2010-6-20