A novel 2D (3,5)-connected coordination framework with Zn-2(COO)(3) SBU

作者：Han Lei^*; Xu Lan Ping; Zhao Wen Na

来源：Journal of Molecular Structure, 2011, 1000(1-3): 58-61.

DOI：10.1016/j.molstruc.2011.05.052

• Coordination framework
• Zn-2(COO)(3) SBU
• (3,5)-Connected network
• 4,4 '-(Hexafluoroisopropylidene)bis(benzoic acid)

A novel 2D Zn(II)-organic coordination framework, [Zn-2(hfipbb)(2)](n) (1) (hfipbb = 4,4'-(hexafluoroisopropylidene)bis(benzoate)), has been synthesized under hydrothermal reaction. Single-crystal X-ray diffraction revealed that 1 is a (3,5)-connected coordination network based on Zn-2(COO)(3) secondary building unit and flexible V-shaped organic linkers. The luminescent property and thermal stability of 1 have also been investigated.

• 出版日期2011-8-10
• 单位浙江大学; 浙江大学宁波理工学院; 宁波大学