Application of a Nickel-Bispidine Complex as Pre-Catalyst for C(sp (2))-C(sp (3)) Bond Formations

作者：Haberberger Michael; Someya Chika I; Company Anna; Irran Elisabeth; Enthaler Stephan^*

来源：Catalysis Letters, 2012, 142(5): 557-565.

DOI：10.1007/s10562-012-0806-4

• Nickel
• Catalysis
• Nitrogen ligand
• Cross coupling

In the present study, the nickel-catalyzed cross coupling of aryl halides with benzyl zinc bromides or dialkyl zinc reagents to create C(sp (2))-C(sp (3)) bonds has been explored. As pre-catalyst the well-defined and easy-accessible (bispidine)Ni(NO3)(2) complex has been applied. After investigation of different reaction parameters a broad scope of C(sp (2))-C(sp (3)) bond formations were feasible under mild reaction conditions. %26lt;br%26gt;.

• 出版日期2012-5