Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

作者:Weiss Charles J; Wiedner Eric S; Roberts John A S; Appel Aaron M*
来源:Chemical communications, 2015, 51(28): 6172-6174.
DOI:10.1039/c5cc01107h

摘要

Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s(-1). These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.

  • 出版日期2015