Dimerization of styrenes catalyzed by PhP(O)HOR/Mn(II)/Co(II)/O2

作者：Liu, Kaijian; Wang, Ying; Li, Peng; Cai, Wenwen; Xiang, Jiannan^*

来源：Catalysis Communications, 2012, 20: 107-110.

DOI：10.1016/j.catcom.2012.01.010

• Dimerization
• Alkyl phenylphosphinate
• Styrenes
• Catalyst system

A methodology for the dimerization of substituted styrenes is reported using a PhP(O)HOR/Mn(II)/Co(II)O-2 catalyst, in which the alkyl phenylphosphinate compound acted as a catalyst rather than a substrate as is generally observed. Mechanistic studies suggested the reaction most likely proceeded via addition-elimination.

• 出版日期2012-4-5
• 单位南方医科大学; 湖南大学