A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide

作者：Son Jung Ho^*; Casey William H

来源：Chemical communications, 2015, 51(64): 12744-12747.

DOI：10.1039/c5cc03782d

Polyoxoniobate clusters that are stable in acidic solutions are rare and particularly useful in industrial processes. Here we report a new pentaphosphate niobate polyoxometalate cluster (TMA)(9)H3Nb9P5O41 center dot 28H(2)O (Nb9P5) that is stable over a wide pH range and that can be converted reversibly into the peroxo form.

• 出版日期2015