Structure maps, classification, and systematization of ABX(2), ABX(3), and ABX(4) halides

作者:Khritokhin N A*; Andreev O V; Lashin V E; Agafonova A V
来源:Russian Journal of Inorganic Chemistry, 2015, 60(6): 692-701.
DOI:10.1134/S0036023615060078

摘要

The criterion Delta E > = E >((AX)) - E >((BX)) enabling the systematization of structures in terms of symmetry categories was proposed for the classification of three-element ionic halides by complex/double type. The adequacy of this approach was verified by the structure maps plotted using the generalized strength parameter. The crystal-chemical properties of the structures of ABX(2), ABX(3), and ABX(4) halides were predicted.

  • 出版日期2015-6

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