Hydrophilic PAN based carbon nanofibres with improved graphitic structure and enhanced mechanical performance using ethylenediamine functionalized graphene

作者：Li Zhenyu; Zabihi Omid; Wang Jinfeng; Li Quanxiang; Wang Jiemin; Lei Weiwei; Naebe Minoo^*

来源：RSC Advances, 2017, 7(5): 2621-2628.

DOI：10.1039/c6ra24719a

Polyacrylonitrile (PAN) reinforced with nano-carbons such as graphene (Gr) and carbon nanotubes (CNTs) provides great opportunity for the development of low-cost and high-performance carbon materials. However, the poor dispersion and weak interaction between the carbon nanofillers and the surrounding PAN matrix prevent the final carbonized materials from reaching their full potential. Herein, we demonstrate a chemical approach using ethylenediamine (EDA) acting as a linker between graphene nanoplatelets and PAN for improved mechanical performance. The as-prepared CNFs exhibit a higher carbon yield and tensile modulus as well as improved graphitic structure compared to pristine PAN and PAN/Gr nanofibres. Furthermore, EDA can act as a N source for N-doping during the carbonization, enabling CNFs with hydrophilicity performance.

• 出版日期2017
• 单位迪肯大学