Unprecedented Interweaving of Hetero-Chiral Single Helical Chains into a 3D Chiral Framework with (10,3) Topology

作者：Zhang Cui Qiao; Fu Feng; Li Dong Sheng^*; Ren Yi Xia; Zhao Xin Ze

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2008, 38(8): 652-656.

DOI：10.1080/15533170802371257

• nickel(II)
• chiral coordination polymers
• hydrothermal synthesis
• helical structure

The title compound, [Ni(dcbp)(H(2)O)(2)](H(2)dcbp = 2,2'-bipyridine-4,4'-dicarboxyacid), was synthesized under hydrothermal conditions. The structure was determined by single-crystal X-ray diffraction and further characterized by elemental analysis, IR, and TGA. The compound crystallized in an orthorhombic system, P2(1)2(1)2(1) space group, a = 6.7665(7) angstrom, b = 12.9047(14) angstrom, c = 13.1848(15) angstrom, beta = 90 degrees. In the compound, each Ni(II) atom exhibits a six-coordinated distorted octahedral geometry. Interestingly, carboxylate group from dcbp ligands bridges between adjacent Ni(II) atoms giving rise to unprecedented interweaving of hetero-chiral single helical chains into a 3D chiral (10, 3) framework.

• 出版日期2008
• 单位三峡大学; 延安大学