Addition of Organometallic Nucleophiles (Carbonylmetallates) to the Allyl Ligand of [(eta(3)-C3H5)Pd(mu-Cl)](2). Synthesis and Structure of (eta(3)-C3H5)Mn(CO)(3)PEt3

作者：Kerscher Thomas; Mihan Shahram; Beck Wolfgang^*

来源：Zeitschrift Fur Naturforschung Section B-a Journal of Chemical Sciences, 2011, 66(8): 861-864.

DOI：10.5560/znb.2011.66b0861

• Allyl
• Carbonyl
• Palladium
• Manganese
• X-Ray Structure Determination

The reaction of the organometallic nucleophile [Mn(CO)(4)-PEt3](-) at the allyl ligand of [(eta(3)-C3H5)Pd(mu-Cl)](2) proceeds by allyl transfer from Pd(II) to Mn(-I) to give [(eta(3)-C3H5)-Mn(CO)(3)PEt3], of which the structure has been determined by X-ray diffraction.

• 出版日期2011-8