A luminescent 2D → 3D Cd complex via π-π* interaction based on bis(4-(1H-imidazol-1-yl)phenyl)amine and 1,3-dicarboxybenzene acid

作者：Zhang, Ming-Dao^*; Zheng, Bao-Hui; Liu, Xin; Huang, Cheng-Yan; Wang, Bin

来源：Crystallography Reports, 2017, 62(6): 923-927.

DOI：10.1134/S106377451706027X

• CRYSTAL-STRUCTURE

A new coordination polymer, {[Cd(BIPA)(1,3-bdc)](DMF)} (n) , based on bis(4-(1H-imidazol-1- yl)phenyl)amine (BIPA) and 1,3-dicarboxybenzene (1,3-H(2)bdc) was synthesized and showing 2D -> 3D structure via pi-pi* interaction of BIPA molecules in the nearby networks in the complex. Investigation of photophysical properties showed that the complex exhibits a strong emission in the range of 350-425 nm (lambda(max) = 375 nm upon excitation at 327 nm).

• 出版日期2017-11
• 单位南京信息工程大学; 中国工程物理研究院; 南京大学