Aldol Condensation and Michael Addition of 4,4-Dimethyl-cyclohexane-1,3-dione and Aromatic Aldehydes. Unconventional Substituent Effects

作者：Kaya Muharrem^*

来源：Chinese Journal of Chemistry, 2011, 29(11): 2355-2360.

DOI：10.1002/cjoc.201180384

• aldol reaction
• Michael addition
• xanthene
• regioselectivity
• substituent effects
• X-ray diffraction

By the cyclization of 4,4-dimethylcyclohexane-1,3-dione with different aromatic aldehydes, the xanthene regioisomers were obtained. The diversity of xanthene isomers could be determined. The electronic and steric effects on aromatic aldehydes could be observed.

• 出版日期2011-11