Unveiling the mechanism of selective gate-driven diffusion of CO2 over N-2 in MFU-4 metal-organic framework

作者：Sastre German^*; van den Bergh Johan; Kapteijn Freek; Denysenko Dmytro; Volkmer Dirk

来源：Dalton Transactions, 2014, 43(25): 9612-9619.

DOI：10.1039/c4dt00365a

The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N-2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small 8Cl-cube pore shows a unique gate-diffusion behaviour with different responses to CO2 and N-2.

• 出版日期2014