Anodic oxidation of silver in 1-butyl-3-methylimidazolium bromide ionic liquid

作者:Grishina E P*; Vladimirova T V; Ramenskaya L M; Shilovskii K S
来源:Russian Journal of Electrochemistry, 2007, 43(2): 234-237.
DOI:10.1134/S1023193507020139

摘要

Electrochemical oxidation of silver in the 1-butyl-3-methylimidazolium bromide ([BMIm]Br) ionic liquid is studied by cyclic voltammetry, chronopotentiometry, chronoammetry, and gravimetry. Two electrode processes irreversibly proceed on the silver electrode in the potential range studied: the formation of compound [BMIm](+)[AgBr2](-), which is soluble in [BMIm]Br, and difficultly soluble AgBr.