A three-dimensional cubic halogen-bonded network

作者:Pfrunder Michael C; Brock Aidan J; Brown Joshua J; Grosjean Arnaud; Ward John; McMurtrie John C*; Clegg Jack K*
来源:Chemical Communications, 2018, 54(32): 3974-3976.
DOI:10.1039/c8cc02178c

摘要

The rational, deliberate design of supramolecular architectures is of great importance for the discovery of complex materials. A three-dimensional cubic halogen-bonded network has been prepared by combination of an octahedral metal-containing halogen bond acceptor and a linear ditopic donor. This material displays alpha-Po pcu topology and is seven-fold interpenetrated. This is the first neutral, metal-containing three-dimensional halogen-bonded network to be reported.

  • 出版日期2018-4-18