A new linear-chain complex based on heptamolybdates with {Ce(H2O)5} linkers

作者：Fu Youzhi^*

来源：Journal of Coordination Chemistry, 2010, 63(11): 1856-1864.

DOI：10.1080/00958972.2010.494725

• Polyoxometalate
• Linear-chain
• Heptamolybdate
• Cerium

A new linear-chain structure based on heptamolybdates with the linkage of {Ce(H2O)5} units, (C6H13N4)2(H3O)[Ce(H2O)5Mo7O24] center dot 4H2O (1) has been synthesized and characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis, and thermogravimetric analysis. Magnetic studies show strong spin-orbital coupling interactions and/or antiferromagnetic interactions within Ce(III) centers.

• 出版日期2010
• 单位白城师范学院