摘要

We develop a new analysis system for identifying orientation of an icosahedral quasicrystal (iQc) in a SEM installed with an electron backscatter diffraction (EBSD) instrument. The system is successfully applied to determine the orientation of any given iQc grain by reading and assigning the Kikuchi bands obtained with the EBSD. This enables us to analyze relative orientations of iQc and alpha Mg grains in a eutectic structure obtained through a unidirectional solidification process for the Mg-Cd-Yb system. According to EBSD analysis, growth direction of the eutectic structure is shown to be clearly parallel to a two-fold axis of the iQc and {10-10} of alpha Mg, and a unique orientation relationship in iQc and alpha Mg grains is verified in all iQc-alpha Mg coexisting regions. The similarity between primary inter-planar spacings of the iQc and alpha Mg phases is a key factor for stabilizing the interface of two phases and favoring the formation of eutectic structure. This stabilization mechanism is supported by a simple argument on the energetics of a quasiperiodic/periodic lattice interface.

  • 出版日期2016-10-15