A simple route to Develop Highly porous Nano Polypyrrole/Reduced Graphene Oxide Composite film for Selective Determination of Dopamine

作者：Arulraj Abraham Daniel; Arunkumar Arumugam; Vijayan Muthunanthevar; Viswanath Kamatchirajan Balaji; Vasantha Vairathevar Sivasamy^*

来源：Electrochimica Acta, 2016, 206: 77-85.

DOI：10.1016/j.electacta.2016.04.134

• Selective sensor
• Polypyrrole
• Electrochemically reduced graphene oxide
• Wettability Test
• Ion exchange
• Porous film
• Human serum samples

A highly selective sensor was developed for dopamine with electrochemically treated sodium dodecyl benzene sulfonate doped nano polypyrrole (ET-SDBS-NPPy)/reduced graphene oxide (RGO) film. First, graphene oxide (GO) was reduced on the electrode surface electrochemically and then, SDBS-NPPy film was polymerized electrochemically on the ERGO coated GCE and bare GCE also. The SDBS-NPPy/ERGO and SDBS-NPPy films were treated electrochemically in phosphate buffer solution to replace macro SDBS-anions by smaller phosphate anions. Then, the physical properties of the above composite films were characterized by scanning electron microscope (SEM) and water wettability test. The replacement of SDBS-anions by phosphate anions leaves porous structure in the polymer films and also increases the hydrophobicity in the films. Then, these composite films were applied for the determination of dopamine in the presence of ascorbic acid and uric acid. Under the optimal conditions, the linear range for dopamine detection is 0.1 mu M-100.0 mu M with the detection limit of 20 nM at S/N = 3. Generally, conducting polypyrrole film could sense ascorbic acid and dopamine simultaneously. However, we have proposed a simple route to synthesis a porous and hydrophobic polypyrrole composite film for selective determination of dopamine in the presence of higher concentration (five orders) of ascorbic acid and uric acid.

• 出版日期2016-7-10