科研之友
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摘要
The adsorption of oligo(sebacoyl peroxide) on Aerosil and MgO and benzoyl peroxide on Fe2O3, Cr2O3, and V2O5 has been studied. It has been established that peroxide adsorption on the considered adsorbents is described by the Langmuir equation. Benzoyl-peroxide adsorption increases in the series Fe2O3 < Cr2O3 < V2O5. The process of thermal decomposition of peroxides in the presence of the listed adsorbents has been studied. The overall reaction of peroxide decomposition comprises two components, i.e., the decomposition processes occurring in a solution and on an adsorbent surface. Kinetic and activation parameters of the thermal-decomposition reactions in the solutions and on the surfaces have been determined.
- 出版日期2013-11
