Layered zirconium phosphate-supported metalloporphyrin: Synthesis and catalytic application

作者：Wang Hai Yan; Ji Wei Dong; Han Da Xiong^*

来源：Chinese Chemical Letters, 2008, 19(11): 1330-1332.

DOI：10.1016/j.cclet.2008.07.024

• MnTMPyP
• Intercalation
• Layered alpha-ZrP
• Catalysis
• Supported material

This paper reports a new route for the preparation of layered alpha-zirconium phosphate (alpha-ZrP)-supported metalloporphyrin MnTMPyP. MnTMPyP was intercalated into alpha-ZrP using alpha-ZrP.BA (i.e. pre-intercalated bultylamine was arranged by a monolayer mode in alpha-ZrP) as a starting material. The catalytic activity of the supported material for homovanillic acid (HVA) oxidation was investigated. The results showed a promising layered material-supported catalyst in catalytic system.

• 出版日期2008-11
• 单位厦门大学