A new way to synthesize superconducting metal-intercalated C-60 and FeSe

作者：Takahei Yuuki; Tomita Keitaro; Itoh Yugo; Ashida Keishi; Lee Ji Hyun; Nishimoto Naoki; Kimura Takumi; Kudo Kazutaka; Nohara Minoru; Kubozono Yoshihiro; Kambe Takashi^*

来源：Scientific Reports, 2016, 6(1): 18931.

DOI：10.1038/srep18931

Doping with the optimum concentration of carriers (electrons or holes) can modify the physical properties of materials. Therefore, improved ways to achieve carrier doping have been pursued extensively for more than 50 years. Metal-intercalation is one of the most important techniques for electron doping of organic / inorganic solids, and has produced superconductors from insulators and metallic solids. The most successful examples are metal-intercalated graphite and C-60 superconductors. Metal intercalation has been performed using solid-reaction and liquid solvent techniques. However, precise control of the quantity of intercalants in the target solids can be difficult to achieve using these methods, as that quantity depends largely on the initial conditions. Here we report an electrochemical method for metal-intercalation, and demonstrate the preparation of superconductors using organic and inorganic materials (C-60 and FeSe). The metal atoms are effectively intercalated into the spaces in C-60 and FeSe solids by supplying an electric current between electrodes in a solvent that includes electrolytes. The recorded superconducting transition temperatures, T-c's, were the same as those of metal-intercalated C-60 and FeSe prepared using solid-reaction or liquid solvent techniques. This technique may open a new avenue in the search for organic / inorganic superconductors.

• 出版日期2016-1-6