Molecular engineering of Ni-/Co-porphyrin multilayers on reduced graphene oxide sheets as bifunctional catalysts for oxygen evolution and oxygen reduction reactions

作者：Sun, Jiqing; Yin, Huajie; Liu, Porun; Wang, Yun; Yao, Xiangdong^*; Tang, Zhiyong^*; Zhao, Huijun

来源：Chemical Science, 2016, 7(9): 5640-5646.

DOI：10.1039/c6sc02083f

• LAYERED DOUBLE HYDROXIDE
• SENSITIZED SOLAR-CELLS
• WATER OXIDATION
• FUNCTIONALIZED GRAPHENE
• ELECTROCATALYST
• COBALT
• ELECTRODES
• INTERMEDIATE
• ADSORPTION
• IMPEDANCE

Ni- and Co-porphyrin multilayers on reduced graphene oxide (rGO) sheets are reported as novel bifunctional catalysts for the oxygen evolution reaction (OER) and the oxygen reduction reaction (ORR). After binding with organic porphyrin molecules, the catalytically-active Ni2+ and Co2+ ions are periodically constructed onto the rGO surfaces via the layer-by-layer (LBL) assembly technique. The resulting catalysts exhibit good performance towards both OER and ORR, which is achieved with accurate control of the composition and thickness of the multilayer structures. This work highlights the potential for the fabrication of efficient electrocatalysts via molecular design.

• 出版日期2016
• 单位国家纳米科学中心