A mesoporous metal-organic framework constructed from a nanosized C-3-symmetric linker and [Cu-24(isophthalate)(24)] cuboctahedra

作者：Yan Yong; Yang Sihai; Blake Alexander J; Lewis William; Poirier Eric; Barnett Sarah A; Champness Neil R; Schroeder Martin

来源：Chemical communications, 2011, 47(36): 9995-9997.

DOI：10.1039/c1cc13170b

The mesoporous framework [Cu-3(L)(H2O)(3)]center dot(DMF)(35)center dot(H2O)(35) (NOTT-119) shows on desolvation a BET surface area of 4118(200) m(2) g(-1), a pore volume of 2.35 cm(3) g(-1), a total H-2 uptake of 101 mg g(-1) at 60 bar, 77 K and a total CH4 uptake of 327 mg g(-1) at 80 bar, 298 K.

• 出版日期2011