A Total Synthesis of Millingtonine A

作者：Wegner Jens^*; Ley Steven V; Kirschning Andreas; Hansen Anne Lene; Garcia Javier Montenegro; Baxendale Ian R

来源：Organic Letters, 2012, 14(3): 696-699.

DOI：10.1021/ol203158p

A total synthesis of millingtonine A, a diglycosylated alkaloid, has been accomplished. Millingtonine A possesses a unique racemic tricyclic core structure not known from any other natural or synthetic source until now. The synthesis features a key bond-forming radical Ueno-Stork cyclization to form the heterocyclic core.

• 出版日期2012-2-3