New developments in chemistry of organometallic porphyrins and their analogs

作者：Vecchi Andrea; Galloni Pierluca^*; Floris Barbara; Nemykin Victor N

来源：Journal of Porphyrins and Phthalocyanines, 2013, 17(3): 165-196.

DOI：10.1142/S1088424613300012

• organometallic porphyrins
• synthesis
• spectroscopy
• redox properties
• photoinduced electron-transfer
• light-harvesting

In this mini-review, new developments in chemistry of organometallic porphyrins and their analogs reported between 2007 and mid 2012 have been discussed. Synthetic strategies for preparation, as well as properties of metallocenyl-type compounds in which organometallic substituents connected to the porphyrinoid via (i) axial coordination; (ii) covalent bond to meso- or beta-pyrrolic position; or (iii) beta,beta%26apos;-fused into the aromatic system as well as porphyrinoids with organometallic fragments sigma-bonded in eta(1)-fashion were overviewed.

• 出版日期2013-3