A unique 3-D chiral Zn(II) coordination framework with 1,2,3-benzenetricarboxyl and 4,4 '-bipyridyl tectons showing 4-connected self-penetrating network and helical character

作者：Ma Lu Fang; Qin Jian Hua; Han Min Le; Wang Li Ya^*; Du Miao

来源：Inorganic Chemistry Communications, 2011, 14(10): 1584-1587.

DOI：10.1016/j.inoche.2011.06.008

• 1,2,3-Benzenetricarboxylic acid
• Hydrothermal synthesis
• 4-connected topological prototype
• Chiral helical character

Hydrothermal reaction of Zn(II) acetate, 4.4'-bipyridyl (bpy) and 1,2,3-benzenetricarboxylic acid (H(3)bta) results in a 3-D coordination framework {[Zn-4(bta)(2)(Hbta)(bpy)(3)](H2O)(3)}(n) (1), which shows the self-penetrating net with a new 4-connected topological prototype and chiral helical character.

• 出版日期2011-10
• 单位洛阳师范学院; 天津师范大学