An enzymatic/acid-catalyzed hybrid process for biodiesel production from soybean oil

作者：Ting Wei Jia; Huang Chun Ming; Giridhar Nair; Wu Wen Teng^*

来源：Journal of the Chinese Institute of Chemical Engineers, 2008, 39(3): 203-210.

DOI：10.1016/j.jcice.2008.01.004

• acid catalyst
• binary immobilized lipase
• biodiesel
• hybrid process

The present study is aimed at developing an enzymatic/acid-catalyzed hybrid process for biodiesel production using soybean oil as feedstock. In the enzymatic hydrolysis, 88% of the oil taken initially was hydrolyzed by binary immobilized lipase after 5 It under optimal conditions. The hydrolysate was further used in acid-catalyzed esterification for biodiesel production and the effects of temperature, catalyst concentration, feedstock to methanol molar ratio, and reaction time on biodiesel conversion were investigated. By using a feedstock to methanol molar ratio of 1: 15 and a sulfuric acid concentration of 2.5%, a biodiesel conversion of 99% was obtained after 12 h of reaction at 50 degrees C. The biodiesel produced by this process met the American Society for Testing and Materials (ASTM) standard. This hybrid process may open a way for biodiesel production using unrefined and used oil as feedstock.

• 出版日期2008-5
• 单位清华大学