Diaquabis(benzyloxyacetato)copper(II)

作者:Sun, Sheng-Li; Chen, Chun-Liang; Gu, Chang-Sheng*; Song, Weng-Dong; Hao, Xiao-Min
来源:ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2008, 64: M691-U713.
DOI:10.1107/S1600536808010593

摘要

In the title mononuclear complex, [Cu(C9H9O3)(2)(H2O)(2)], the Cu-II ion, located on an inversion center, is hexacoordinated by four O atoms from two benzyloxyacetate ligands [ Cu - O = 1.9420 ( 14) and 2.2922 ( 14) angstrom] and two water molecules [ Cu O = 2.0157 ( 15) angstrom] in a distorted octahedral geometry. In the crystal structure, intermolecular O-H center dot center dot center dot O hydrogen bonds link the molecules into layers parallel to the bc plane.