Low-temperature selective catalytic reduction of NO with NH3 over Ni-Mn-Ox catalysts

作者：Zhang, Peipei; Sun, Yan^*; Su, Wei; Wei, Yajuan; Liu, Jia

来源：RSC Advances, 2016, 6(109): 107270-107277.

DOI：10.1039/c6ra21267k

• OXIDE CATALYSTS
• DOPED MN/TIO2
• METAL-OXIDES
• MIXED OXIDES
• PERFORMANCE
• SCR
• MECHANISM
• NITROGEN
• NH3-SCR
• CATHODE

A series of manganese-nickel oxide catalysts with different Ni/Mn ratios were prepared using a hard template method with KIT-6 as the template. These mesoporous nanomaterials were characterized using Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy and X-ray photoelectron spectroscopy (XPS). The low temperature selective catalytic reduction (SCR) of NO with NH3 in the presence of excess O-2 was investigated. At a gas hourly space velocity (GHSV) of 38 000 h(-1), the Ni(1 : 3)-MnOx (Ni/Mn = 1 : 3) catalyst had the highest activity, giving an NO conversion of 81.3% at 60 degrees C and 100% from 100 to 220 degrees C. The Ni(1 : 3)-MnOx catalyst had high N-2 selectivity, excellent stability, good H2O resistance and functioned well at various GHSVs. The BET, XRD and XPS results showed that the Ni(1 : 3)-MnOx catalysts had large surface areas (187 m(2) g(-1)) and that a more amorphous phase was formed as the nickel content was increased. The Mn4+ and chemisorbed oxygen are the main active species for the SCR reaction. These properties are desirable for low-temperature SCR catalysts.

• 出版日期2016
• 单位天津大学