Stepwise fabrication of donor/acceptor thin films with a charge-transfer molecular wire motif

作者：Sekine Yoshihiro; Yokoyama Taiga; Hoshino Norihisa; Ishizaki Manabu; Kanaizuka Katsuhiko; Akutagawa Tomoyuki; Haga Masa Aki; Miyasaka Hitoshi^*

来源：Chemical Communications, 2016, 52(97): 13983-13986.

DOI：10.1039/c6cc08310b

Novel thin films composed of a donor (D)/acceptor (A) charge-transfer chain compound were fabricated by a layer-by-layer technique using complexation of a paddlewheel-type diruthenium(II, II) complex with an N, N'-dicyanoquinonediimine derivative on an ITO substrate with a pyridine-substituted phosphonate anchor. The stepwise growth of an electron-transfer D+A(-)-chain thin film was confirmed.

• 出版日期2016