Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin](+)[Co(CO)(4)](-) catalyst

作者：Lamb Jessica R^*; Jung Yukyung; Coates Geoffrey W

来源：Organic Chemistry Frontiers, 2015, 2(4): 346-349.

DOI：10.1039/c4qo00324a

A Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using a well-defined aluminum porphyrin catalyst is reported. This reaction shows good functional group tolerance under mild reaction conditions to selectively give methyl ketones in excellent yields.

• 出版日期2015