A novel mechanism of ultrathin SOI synthesis by extremely low-energy hot O+ implantation

作者:Hoshino Yasushi*; Yachida Gosuke; Inoue Kodai; Toyohara Taiga; Nakata Jyoji
来源:Journal of Physics D: Applied Physics , 2016, 49(31): 315106.
DOI:10.1088/0022-3727/49/31/315106

摘要

Extremely low-energy oxygen implantations at 10 keV in silicon were challengingly performed to directly synthesize ultrathin silicon-on-insulator (SOI) structure separated by a buried oxide (BOX) layer. We quantitatively investigated the optimum condition and the formation mechanism of homogeneous and continuous stoichiometric SOI/BOX structure. In this study, oxygen ions were implanted into Si(0 0 1) substrates with keeping the temperatures at 500, 800, and 1000 degrees C with ion-fluences from 0.5 to 2.0 x 10(17) ions cm(-2). These samples were then postannealed at high temperatures from 950 to 1150 degrees C in Ar ambient for several hours. We found that ultrathin stoichiometric SOI/BOX structure with less than 20 nm thick was synthesized by oxygen implantation with an ion dose of 1.0 x 10(17) ions cm(-2) from 500 degrees C to 800 degrees C followed by annealing at a significantly low temperature of 1050 degrees C for 5 h. According to the RBS-channeling analysis, the crystallinity was excellent as quality as that of the SOI structure formed by a wafer-bonding method. We found that the BOX layer was finally formed around the deeper end of the oxygen distribution in the as-implanted sample, though the depth of the BOX formation was much deeper than the projected range of oxygen and the damage peak of silicon. The formation process of the SOI/BOX structure proposed so far could not be applicable to the present conditions for ultrathin SOI/BOX synthesis by extremely low-energy implantation followed by low-temperature annealing. We thus suggested a novel mechanism of the ultrathin SOI/BOX synthesis as follows. The mechanism during the thermal treatment was demonstrated that the recrystallization of the damaged Si layers induced by ion irradiation took place from the very surface with relatively less irradiation-damages toward deeper layers with sweeping interstitial oxygen atoms, and the condensed oxygen atoms finally synthesized the stoichiometric BOX layer.

  • 出版日期2016-8-10