A silver(I) coordinated phenanthroline-based polymer with high ethylene/ethane adsorption selectivity

作者：Yu Chao; Cowan Matthew G; Noble Richard D; Zhang Wei^*

来源：Chemical communications, 2014, 50(43): 5745-5747.

DOI：10.1039/c4cc02143f

We report a non-porous silver(I) coordinated phenanthroline-based polymer, which exhibits a high ideal ethylene/ethane adsorption selectivity (15/1) and high ethylene uptake (5.0 mmol g(-1)) at ambient temperature and pressure. Both silver(I) coordination and polymer structures are important for the high uptake of ethylene.

• 出版日期2014