Activation of Methane on NiO Nanoparticles with Different Morphologies

作者：Martins Ruth L; Schmal Martin^*

来源：Journal of the Brazilian Chemical Society, 2014, 25(12): 2399-2408.

DOI：10.5935/0103-5053.20140266

• NiO
• nanoparticles
• H-2 production
• carbon nanofilaments

Nanostructured surfaces can be defined as substrates in which the typical features have dimensions in the range of 1-100 nm. The recent focus of interest in these systems is based on the fact that interesting novel properties (catalytic, magnetic, ferroelectric, mechanical, optical and electronic) are developed as a result of the dimension reductions of these substrates. This paper describes the catalytic methane decomposition into hydrogen and carbon nanofilaments on unsupported Ni catalysts prepared from different methodologies, with controlled particle size and morphologies. Ni catalyst supported on zirconia was also used for performance comparison. For the unsupported catalysts, it was observed strong dependency of catalyst activities with particle size of nickel oxide precursors and their morphologies. Although all of them presented crystallite sizes with nanometric dimensions, only those prepared with ethylene glycol, NiEG, and by hydrothermal condition, NiHT, exhibited the same performance as the supported catalyst (activity and stability), 25NiZ. Catalyst synthesized in the presence of dimethylglyoxime, NiDMG, was less active and deactivated with time on stream.

• 出版日期2014-12