Macrocyclic silver coordination compounds with bis[4-(pyridine-2-yl)pyrimidin-2-ylthio]methane: crystal structures and luminescent properties

作者：Zhu Hai Bin^*; Zhang Shu Ying; Lu Xin; Yang Wen Na

来源：Journal of Chemical Research, 2011, (3): 144-146.

DOI：10.3184/174751911X12973456175518

• dinuclear
• macrocyclic
• silver coordination polymers
• photoluminescence
• X-ray structures

Reaction of AgX2 (X = NO3-, BF4-) with bis[4-(pyridine-2-yl)pyrimidin-2-ylthio] methane (2-bppt) gave two macrocyclic dinuclear silver coordination compounds [Ag-2{mu-(2-bppt)}(2)]X-2 (X= NO3- or BF4-). Non-classical hydrogen bonding interactions as well as weak aromatic stacking forces are involved in their packing structures. Both compounds show intense photoluminescence governed principally by the 2-bppt ligand itself.

• 出版日期2011-3
• 单位东南大学