A(2+) Cation Control of Chiral Domain Formation in A(TiO)Cu-4(PO4)(4) (A = Ba, Sr)

作者：Kimura Kenta^*; Sera Masakazu; Kimura Tsuyoshi

来源：Inorganic Chemistry, 2016, 55(3): 1002-1004.

DOI：10.1021/acs.inorgchem.5b02622

Single crystals of two novel tetragonal chiral materials, A(TiO)Cu-4(PO4)(4) (A = Ba, Sr), were grown from Na2Mo2O7 flux, and their crystal and chiral domain structures were characterized. Polarized-light microscopy studies of the chiral domain structures in the crystals show that Ba(TiO)Cu-4(PO4)(4) mostly hosts a multidomain state, while a monodomain state predominantly appears in Sr(TiO)Cu-4(PO4)(4). To explain this striking difference, we quantified the chirality strength of these materials by comparing atomic positions in the chiral and nearest-achiral crystal structures, revealing larger chirality strength in Sr(TiO)Cu-4(PO4)(4) than in Ba(TiO)Cu-4(PO4)(4). Our proposed mechanisms linking the chirality strength and domain formation can account for the different occurrence frequency of chiral domains in this system.

• 出版日期2016-2-1