Non-Innocent Property of Tridentate Ligand in Novel Cobalt Complex : Crystal Structure and Evidences for Cobalt(II) Phenoxyl Radical Complex Formation

作者：Dhara Ashish Kumar; Kumar Kapil; Kumari Sheela; Singh Udai P; Ghosh Kaushik^*

来源：ChemistrySelect, 2016, 1(13): 3933-3937.

DOI：10.1002/slct.201600647

• Non-innocent tridentate ligand
• cobalt complex
• phenoxyl radical complex
• crystal structure
• DFT/TD-DFT calculation

A phenoxyl radical complex [Co-II(L)(L+)]NO3 (where LH=(E)-2,4-di-tert-butyl-6-((2-phenyl-2-(pyridin-2-yl)hydrazono) methyl)phenol and H=dissociable proton) was synthesized at room temperature in aerobic condition and was characterized. Crystal structure, UV-Vis-NIR and H-1-NMR spectra, magnetic properties and electrochemical studies authenticated the presence of Co (II) phenoxyl radical complex.

• 出版日期2016-8-16