A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor-acceptor interactions

作者：Mochida Tomoyuki^*; Funasako Yusuke; Takahashi Kazuyuki; Inokuchi Makoto; Sakurai Takahiro; Ikeda Shohei; Ohta Hitoshi; Mori Hatsumi; Uruichi Mikio

来源：Chemical communications, 2014, 50(87): 13370-13372.

DOI：10.1039/c4cc06888b

[Dineopentyl-biferrocene](2)[CI(1)TCNQ](7), which has an unprecedented high donor-acceptor ratio of 2:7, contains a linear paramagnetic hexamer of Cl(1)TCNQ. Both the donor and acceptor molecules exhibit charge disproportionation in the crystal through mutual electrostatic interactions.

• 出版日期2014-11-11