A 3D porous metal-organic framework constructed of 1D zigzag and helical chains exhibiting selective anion exchange

作者：Wang Dengxu; He Haiyan; Chen Xiaohui; Feng Shengyu^*; Niu Yuzhong; Sun Daofeng

来源：CrystEngComm, 2010, 12(4): 1041-1043.

DOI：10.1039/b910988a

Slow diffusion of AgClO4(4) with Me(2)Si [(4-(Im-1-yl)Ph](2) (BIPS) yields the crystalline complex 1 with a 3D-braided porous metal organic framework via self-assembly of two series of 1D polymer chains through both braiding and interpenetrating. Complex 1 consists of two distinct kinds of channels with different sizes and shapes along a and b directions occupied by perchlorate anions and water molecules.

• 出版日期2010
• 单位山东大学