Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic, and modeling standpoint

作者：Rebelo Luis Paulo N^*; Lopes Jose N Canongia; Esperanca Jose M S S; Guedes Henrique J R; Lachwa Joanna; Najdanovic Visak Vesna; Visak Zoran P

来源：Accounts of Chemical Research, 2007, 40(11): 1114-1121.

DOI：10.1021/ar7000556

The fascinating, complex behavior of ionic liquids is analyzed using a molecular perspective that emphasizes the doubly dual nature of ionic liquids underlying the existence of cations and anions forming high- and low-charge-density regions. Our work bridges the liquid, gas, and solid phases spanning 5 years of research on themes as diverse as the vaporization, liquid-liquid demixing, solidification, and thermophysical behavior of ionic liquids and their mixtures and solutions.

• 出版日期2007-11